Class 12th Chemistry 2017 Set2 Delhi Board Paper Solution

How the following conversions can be carried out?

(i) Propene to propan-1-ol

(ii) Ethanol to but-1-yne

(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol

(v) Benzene to 4-bromonitrobenzene

(vi) Benzyl alcohol to 2-phenylethanoic acid

(vii) Ethanol to propanenitrile

(viii) Aniline to chlorobenzene

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane

(xi) Ethyl chloride to propanoic acid

(xii) But-1-ene to n-butyliodide

(xiii) 2-Chloropropane to 1-propanol

(xiv) Isopropyl alcohol to iodoform

(xv) Chlorobenzene to p-nitrophenol

(xvi) 2-Bromopropane to 1-bromopropane

(xvii) Chloroethane to butane

(xviii) Benzene to diphenyl

(xix) tert-Butyl bromide to isobutyl bromide

(xx) Aniline to phenylisocyanide

Give simple chemical tests to distinguish between the following pairs of compounds.

(i) Propanal and Propanone

(ii) Acetophenone and Benzophenone

(iii) Phenol and Benzoic acid

(iv) Benzoic acid and Ethyl benzoate

(v) Pentan-2-one and Pentan-3-one

(vi) Benzaldehyde and Acetophenone

(vii) Ethanal and Propanal

A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.

A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL^-1, then what shall be the molarity of the solution?

Henry's law constant for CO₂ in water is 1.67 x 10⁸Pa at 298 K. Calculate the quantity of CO₂in 500 mL of soda water when packed under 2.5 atm CO₂ pressure at 298 K.

Calculate the mass of a non-volatile solute (molar mass 40 g mol^-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.

The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.

Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.

How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na₂CO₃ and NaHCO₃ containing equimolar amounts of both?

If NaCl is doped with 10^-3mol % of SrCl₂, what is the concentration of cation vacancies?

Consider the reaction:

Cr₂ O₇^2- + 14H⁺ + 6e^- → Cr³⁺ + 8H₂O 

What is the quantity of electricity in coulombs needed to reduce 1 mol of Cr₂ O₇^2-?

What are essential and non-essential amino acids? Give two examples ofeach type.

Why are Mn²⁺compounds more stable than Fe²⁺ towards oxidation to their +3 state?

What is the effect of temperature on the rate constant of a reaction? How can this temperature effect on rate constant be represented quantitatively?

The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:

Predict the products of electrolysis in each of the following:

(i) An aqueous solution of AgNO₃ with silver electrodes.

(ii) An aqueous solution of AgNO₃with platinum electrodes.

(iii) A dilute solution of H₂SO₄with platinum electrodes.

(iv) An aqueous solution of CuCl₂ with platinum electrodes.

To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.

How are vitamins classified? Name the vitamin responsible for thecoagulation of blood.

The decomposition of NH₃on platinum surface is zero order reaction. What are the rates of production of N₂and H₂if k = 2.5 x 10^-4mol^-1L s^-1?

A solution of [Ni(H₂O)₆]²⁺ is green but a solution of [Ni(CN)₄]^2- is colourless. Explain.