After watching a programme on TV about the presence of carcinogens (cancer causing agents) Potassium bromate and Potassium iodate in bread and other bakery products, Rupali a class XII student decided to make others aware about adverse affect of these carcinogens in foods. She consulted the school principal and requested him to instruct canteen contactor to stop selling sandwiches, pizzas, burgers and other bakery products to the students. The Principal took an immediate action and instructed to canteen contractor to replace the bakery products with some protein and vitamin rich food like fruit,salads,sprouts etc.The decision was welcomed by the parents and the students.
After reading the above passage, answer the following questions:
(a) What are the values (at least two) displayed by the Rupali?
(b) Which Polysaccharide component of carbohydrates is commonly present in bread?
(c) Write the two types of secondary structures of proteins.
(d) Give two examples of water solube vitamins.
(a)
1.To aware about adverse effect of carcinogen present in bread.
2.To Replace the bakery product with some protein and vitamin rich food like fruits, salads etc.
(b) Starch, Glycogen
(c) Alpha heix, Beta pleated sheet
(d) Riboflavin, Thiamine
Give simple chemical tests to distinguish between the following pairs of compounds.
(i) Propanal and Propanone
(ii) Acetophenone and Benzophenone
(iii) Phenol and Benzoic acid
(iv) Benzoic acid and Ethyl benzoate
(v) Pentan-2-one and Pentan-3-one
(vi) Benzaldehyde and Acetophenone
(vii) Ethanal and Propanal
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL-1, then what shall be the molarity of the solution?
Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour phase.
Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and NaHCO3 containing equimolar amounts of both?
If NaCl is doped with 10-3mol % of SrCl2, what is the concentration of cation vacancies?
Explain why Cu+ ion is not stable in aqueous solutions?
Use Hund's rule to derive the electronic configuration of Ce3+ ion and calculate its magnetic moment on the basis of 'spin-only' formula.
List the important sources of sulphur.
The treatment of alkyl chlorides with aqueous KOH leads to the formation of alcohols but in the presence of alcoholic KOH, alkenes are major products. Explain.
State the role of silica in the metallurgy of copper.
If the solubility product of CuS is 6 x 10-16, calculate the maximum molarity of CuS in aqueous solution.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number.
Calculate
(a) molality
(b) molarity and
(c) mole
fraction of KI if the density of 20% (mass/mass) aqueous KI is 1.202 g mL-1.
Give the structures and IUPAC names of monohydric phenols of molecular formula, C7H8O.